The description describes the $29.99 "Early Access" Dota 2 so I think it comes with the items as well.
If you don't have many (or any) Valve games then you can't go wrong with the Valve Complete Pack. If you're only considering it for the Dota 2 "Early Access" then it's not really worth it.
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Does Valve Complete Pack include Dota 2 early access items?
Items Included in Dota 2 early access:
Mighty Boar
Stoic Mask of the High Plains
Wolf Cape of the High Plains
Aspect Wraps of the High Plains
Long-Fang the Grey Blade
Tayrnhelm of the Swordmaster
Girth of the Swordmaster
Fluted Guard of the Swordmaster
Grip of the Swordmaster
Staff of the Old Doctor
Wooden Fetish Mask
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