I'm in the same situation at the moment. You need to open a support ticket to Steam and ask them to remove your phone number.
I sent them a ticket on Friday, got a response on Monday that they need proof of legitimacy (like a paypal receipt for any purchase or a picture of a box case with a key i activated on the account). Haven't heard back from them since
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Settings -> Account -> Manage Steam Guard Account Security. There's an option to remove/ disable Mobile Auth. If you already have the new phone, I don't see any reason you wouldn't be able to remove the old and then just set up the new one from scratch.
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