Hello Jhrlambert
Firstly, welcome to Steamgifts :)
It's not possible to gift games that are already on your Steam account. Games can be bought from 3rd party sites or given as a gift from the Steam store (be careful of the price differences between regions that may stop you from doing this). The other posts in the Deals section of this site have links to 3rd party sites that could be used - https://www.steamgifts.com/discussions/deals
Also, please remember:
All giveaways must be for Steam redeemable gifts or Steam redeemable keys.
I suggest reading the FAQ and Guidelines.
Useful guides:
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i would just add that Fantical is my good to place to get keys - https://www.fanatical.com/en/bundle/games - price high to low can get you some great games for £1 for giveaways
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Technically they are. Everything in your steam library is not owned by you, your basically renting a license to use the game.
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Of course you can. You just post here your Steam login and password... and bots steal your account
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The question is in the title already :)
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