If it's on the list (you're able to select the game/DLC), you're allowed to give it.
The exception being a game/DLC that went free just recently and the mods haven't had time to update the list - in that case it'd be against the rules if you deliberately give it away though you obtained it as part of a mass drop of free keys. Usually free games are removed from the list within a few days.
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If it's a gift you can, or if the DLC has achievements you can or if you add the winner as a friend you can...
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Are we allowed to give DLCs in Giveaways?
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