You can try commenting on the giveaway that you won, saying that you received the wrong key.
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No, just wait 7 seven days and mark not received. Then maybe he'll contact you himself
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If he has any open giveaways or trades or other threads, you can post there and he will get a notification. (I'm not sure if he gets a notifiation if you post in his closed giveaway).
Other than that or through Steam - no, there's no other way.
Hope that helped.
Cheers =)
Edit: okay, so you do get a notification if someone posts in your closed giveaway.
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Crazy question. What game was the giveaway for, and what did they send you? They might have created a giveaway for a free game under the title of another. Against the rules, obviously, but doesn't stop some idiots.
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If it was from one of the latest Humble Bundles, they may have mixed up the DLC key with the base game key. Which can happen. Hopefully you get in contact with the individual and can get it sorted out.
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Mark "not received" after the week is up. He or she will have to get in touch with you to "fix" that.
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I won a giveaway but the creator has sent me a wrong key. I tried to contact him via Steam but has not accepted my friend request. There is another way to contact him?
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